Evaluation of gadolinium ion emission characteristics in aqueous solution using laser-induced luminescence spectroscopy

Not scheduled
20m
A102 (Agora, University of Jyväskylä, Finland)

A102

Agora, University of Jyväskylä, Finland

Agora, Mattilanniemi 2, 40100 Jyväskylä, Finland
Poster Presentation Poster Sessions

Speaker

Yoshihiro Iwata (Japan Atomic Energy Agency)

Description

Gadolinium (Gd) is a rare earth metal belonging to the lanthanide series. Taking advantage of its large neutron absorption cross section and high $\gamma$-ray energy ($\sim$8 MeV in total) of (n,$\gamma$) reaction, Gd sulfate is dissolved in the Super-Kamiokande (SK) 50 kton water Cherenkov detector, which is being carried out as the SK-Gd project, to increase the detection sensitivity of supernova relic neutrino events.
In this work, the emission characteristics of Gd$^{3+}$ ions in aqueous solution such as quenching by anions and excitation spectra are studied using laser-induced luminescence spectroscopy. A simulation study is performed to estimate the Gd$^{3+}$ emission background rate from cosmic muons in the SK-Gd experiment. We are developing a portable monitoring system based on this spectroscopic technique to enable real-time measurements of Gd$^{3+}$ concentration and emission lifetime without contamination during water sampling.

Author

Yoshihiro Iwata (Japan Atomic Energy Agency)

Co-authors

Hiroyuki Sekiya Chikara Ito (Japan Atomic Energy Agency)

Presentation materials

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